The research group of chemist Miriam Unterlass, CeMM Adjunct Principal Investigator and professor the University of Konstanz, succeeded in producing organic and inorganic substances in a single process using an environmentally friendly method.

The production of chemical substances normally requires environmentally harmful solvents. After the research group of Miriam Unterlass, professor of Solid State chemistry at the University of Konstanz and CeMM Adjunct Principal Investigator, produced organic substances without harmful substances for the first time by heating them in hot water, the researchers can now chalk up another success: Through hydrothermal synthesis, they succeed-ed in jointly forming and combining organic and inorganic substances in the same reaction vessel. Specifically: an inorganic solid that encloses organic dye molecules. When exposed to light, which is by and large the most environmentally friendly energy resource, the hybrid material functions like a catalyst, i.e., a photocatalyst. Since the photocatalyst is a solid, it can be used multiple times. The study was recently published online by the Journal of Materials Chemistry A at https://doi.org/10.1039/D1TA03214C. In the printed edition of the journal (Issue 24), the study will be featured on the cover page, which is reflecting a special appreciation.

Hydrothermal synthesis, i.e. the production of materials under pressure in hot water, is copied from nature. In underground hot water reservoirs, for example, rock crystals form as the atoms dissolved in the hot water react with each other, first forming molecules and then crystals. In the same way, inorganic molecules can be produced in synthetic chemistry – and as described in a study on the environmentally friendly process in the synthesis of organic substances from 2021 by Miriam Unterlass – also organic molecules without toxic solvents.

Environmentally friendly synergy of both processes
An environmentally friendly synergy of both methods arises from the current results, in which first author Dr Hipassia Moura, a postdoctoral researcher in Miriam Unterlass' team, plays a major role. Miriam Unterlass: "In our work we show that it is possible to form inorganic and organic substances at the same time in ‘hot water’, and that something useful comes out of it."

The fact that the hybrid material can be produced completely without toxic solvents is all the more remarkable because the chemist's research team works with dye molecules that normally require highly toxic chemicals for their synthesis. The core of the new substance, which was created in hot water, is formed by dye molecules that exist as a solution, while the material surrounding them has the properties of a solid. The result is a solid that behaves like a solution in terms of optical properties.

Reusable catalyst

Dyes as solutions have very specific properties. The dye molecules used by Miriam Unterlass' research team are able to absorb light and thus catalyze reactions. This process is similar to photosynthesis in plants, where it is also pigments that absorb the light needed for photosynthesis. Unlike a solution that has to be disposed of after use, the hybrid material has the added advantage that it can be used again and again as a catalyst, because it is like a solid on the outside. 

The research team's specific target for application are small organic molecules that play a role in pharmaceuticals. In principle, however, the method is relevant for various chemical reactions and thus the production of countless synthetic products. And while water still has to be heated for the synthesis of the hybrid material, only light energy is required for the catalytic effect. "Light is the best resource we have. Light cannot be used up", says Miriam Unterlass.

The Study “Green Hydrothermal Synthesis Yields Perylenebisimide-SiO2 Hybrid Materi-als with Solution-Like Fluorescence and Photoredox Activity” was published on June 13, 2022, in the Journal of Materials Chemistry A online, doi: https://doi.org/10.1039/D1TA03214C

Authors: H.M. Moura, H. Peterlik & M. M. Unterlass

Funding: This study was funded by grant START Y1037-N38 from the Austrian Science Fund (FWF).